Thanks for very quick response!
Unfortunately, Webdriver accepts the code, but the output doesn't work... I just see the normal Chrome (Microsoft Edge) window, as I start it without the "app-id" argument. Any ideas?
$sDesiredCapabilities = '{"capabilities": {"alwaysMatch": {"ms:edgeOptions": {"args":["app-id=mkjkjhffnfhefonpoajpeaohoocodfig"], "w3c": true, "useAutomationExtension": false}}}}'
Output of chrome.log-File: